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No, it's not determined at the beginning of the game. For example, if you keep reloading every time you meet a Dialga, it will eventually become shiny. :)
Here are the Pokemon that I am after currently. Just post what you want and I'll see if I have it. I can also trade items with Pokemon too. The ones that are glowing are the ones that I want the most. ^ ^ Bold Pokemon are the newest. But, most of these are rare so I don't think you'll have them...
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