Alright, I'll join in.
Name: Shantae
Appearance: A tanned skin with long purple hair (Ponytail) and a red genie outfit.
Game(s) they appear in: Shantae Series
Moveset: Flintlock Pistol (Neutral Special), Risky's Boots (Side Special), Pirate Hat (Up Special), Transformation (Down Special), Dance Parlor Special (Final Smash)
Other: With her transformation she can change between a Money with headbutts, an Elephant for charges and a Mermaid for tail swipes. She cannot use the Screw Attack though.
Name: Bayonetta
Appearance: Long black hair with fair skin, curves and a skin-tight black outfit and a pair of boots.
Game(s) they appear in: Bayonetta Series.
Moveset: Bullet Climax (Neutral Special), Heel Slide (Side Special), Witch Twist (Up Special), Witch Time (Down Special), Infernal Climax (Final Smash)
Other: Second character to use hair for combat.
Name: Pikachu
Appearance: A yellow mouse with red circle cheeks and a lightning-bolt shaped tail.
Game(s): Pokemon Series
Moveset: Thunder Jolt (Neutral Special), Skull Bash (Side Special), Quick Attack (Up Special), Down Special (Thunder), Volt Tackle (Final Smash)
Other: It should be called "Thunder Shock" rather than Thunder Jolt.